Orange G

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Orange G

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This article is compiled based on the United States Pharmacopeia (USP) – 2025 Edition

Issued and maintained by the United States Pharmacopeial Convention (USP)

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(the sodium salt of azobenzene-betanaphthol disulfonic acid), C6H5N:NC10H4(OH)(SO3Na)2 -2,6,8 452.37 CAS RN®: 1936-15-8.

Orange to brick-red powder or dark red crystals. Readily soluble in water, yielding an orange-yellow solution; slightly soluble in alcohol; insoluble in ether and in chloroform. The addition of tannic acid TS to its 1 in 500 solution causes no precipitation (acid color). The addition of hydrochloric acid to a mixture of 500 mg of zinc dust and 10 mL of its 1 in 500 solution produces decolorization. When filtered, the colorless filtrate, on standing exposed to air, does not regain its original color (presence of azo-group). When heated, orange G does not de agrate (distinction from nitro colors). The addition of barium or calcium chloride TS to a concentrated solution of orange G produces a colored, crystalline precipitate. The addition of hydrochloric acid to its 1 in 500 solution produces no change; the addition of sodium hydroxide TS to a similar solution produces a yellowish red to a Bordeaux color but no precipitation. Orange G dissolves in sulfuric acid with an orange to yellowish-red color. No change in color results upon diluting the solution cautiously with water.

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