0.1 N Potassium Bromate VS

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0.1 N Potassium Bromate VS

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This article is compiled based on the United States Pharmacopeia (USP) – 2025 Edition

Issued and maintained by the United States Pharmacopeial Convention (USP)

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KBrO3,          167.00

2.784 g in 1000 mL

Dissolve 2.784 g of potassium bromate in water to make 1000 mL.

Standardization: Transfer an accurately measured volume of about 40 mL of the solution to a glass-stoppered flask, add 3 g of potassium jodide, and follow with 3 mL of hydrochloric acid. Allow to stand for 5 min, then titrate the liberated iodine with 0.1 N sodium thiosulfate VS, adding 3 mL of starch TS as the endpoint is approached. Correct for a blank run on the same quantities of the same reagents, and calculate the normality.

N = (ml Na2S2O3 x N Na2S2O3)/mL KBrO3 Solution

[NOTE-If this volumetric solution is used in a qualitative application such as pH adjustment, dissolution medium, or diluent, its standardization is not required.]

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