0.05 M Potassium Iodate VS

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0.05 M Potassium Iodate VS

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This article is compiled based on the United States Pharmacopeia (USP) – 2025 Edition

Issued and maintained by the United States Pharmacopeial Convention (USP)

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KIO3,               214.00

10.70 g in 1000 mL

Dissolve 10.700 g of potassium iodate, previously dried at 110° to constant weight, in water to make 1000.0 mL.

Standardization: To 15.0 mL of solution in a 250-mL iodine flask, add 3 g of potassium iodide and 3 mL of hydrochloric acid previously diluted with 10 mL of water. Stopper immediately, and allow to stand in the dark for 5 min. Then add 50 mL of cold water, and titrate the liberated iodine with freshly standardized 0.1 N sodium thiosulfate. Add 3 mL of starch indicator solution near the end of the titration, and continue to the absence of the blue-starch-iodine complex.

M = (mL x N Na2S2O3)/mL KIO3 x 6

[NOTE-If this volumetric solution is used in a qualitative application such as pH adjustment, dissolution medium, or diluent, its standardization is not required.]

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